2022

133

Asymmetric Alkynylation of Tertiary Carbon-Centered Radical via Copper-Catalyzed Radical Relay
Dunqi Wu, Lianqian Wu, Pinhong Chen, Guosheng Liu* Chin. J. Chem. 2022, 10.1002/cjoc.202200108.

132

Palladium(II)-Catalyzed Enantioselective Hydrooxygenation of Unactivated Terminal Alkenes
Xintuo Yang, Xiang Li, Pinhong Chen*, Guosheng Liu* J. Am. Chem. Soc. 2022, 144, 7972–7977.

131

Copper-Catalyzed Enantioselective Radical Chlorination of Alkenes
Dunqi Wu, Wenzheng Fan, Lianqian Wu, Pinhong Chen, Guosheng Liu* ACS Catal. 2022, 12, 5284–5291.

130

Palladium-Catalyzed Intermolecular Carbonylation-Based Difunctionalization of Alkenes
Bing Tian, Pinhong Chen, Guosheng Liu* Synlett 2022, DOI: 10.1055/s-0040-1719898.

129

Palladium-catalyzed intermolecular alkynylcarbonylation of unactivated alkenes: an easy access to β-alkynylcarboxylic esters
Xiang Li, Pinhong Chen,* Guosheng Liu* Chem. Commun. 2022, 58, 2544-2547.

128

Copper-catalyzed radical relay in C(sp3)–H functionalization
Zuxiao Zhang, Pinhong Chen, Guosheng Liu* Chem. Soc. Rev. 2022, 51, 1640-1658.

127

Catalytic remote hydrohalogenation of internal alkenes
Xiang Li,# Jianbo Jin,# Pinhong Chen, Guosheng Liu* Nat. Chem. 2022, 14, 425–432.

126

Copper-catalysed asymmetric radical cyanation
Fei Wang, Pinhong Chen, Guosheng Liu* Nat. Synth. 2022, 1, 107–116.

2021

125

Enantioselective Copper-Catalyzed Radical Cyanation of Propargylic C–H Bonds: Easy Access to Chiral Allenyl Nitriles
Ronghua Lu#, Tilong Yang#, Xin Chen, Wenzheng Fan, Pinhong Chen, Zhenyang Lin,* Guosheng Liu* J. Am. Chem. Soc. 2021, 143, 14451–14457.

124

Asymmetric Palladium-Catalyzed Oxycarbonylation of Terminal Alkenes: Efficient Access to β-Hydroxy Alkylcarboxylic Acids
Bing Tian, Xiang Li, Pinhong Chen, Guosheng Liu*Angew. Chem. Int. Ed. 2021, 60, 14881–14886.

123

Anionic Bisoxazoline Ligands Enable Copper-Catalyzed Asymmetric Radical Azidation of Acrylamides
Lianqian Wu,# Zhihan Zhang,# Dunqi Wu,# Fei Wang, Pinhong Chen, Zhenyang Lin,* Guosheng Liu* Angew. Chem. Int. Ed. 2021, 60, 6997 –7001. (# These author contributed equally to this work)

122

Palladium-Catalysed Enantioselective Diacetoxylation of Terminal Alkenes
Bing Tian, Pinhong Chen , Xuebing Leng, Guosheng Liu* Nat. Catal. 2021, 4, 172-179.

121

Enantioselective Intermolecular Aminoalkynylation of Styrenes via Copper-Catalyzed Radical Relay
Zhoumi Hu, Liang Fu, Pinhong Chen, Weiguo Cao,* Guosheng Liu* Org. Lett. 2020, 23, 129-134.

120

Enantioselective Arylcyanation of Styrenes via Copper-Catalyzed Radical Relay.
Weiwen Zhuang, Pinhong Chen, Guosheng Liu* Chin. J. Chem. 2021, 39, 50-54.

2020

119

Ligand-Controlled Regioselective Pd-Catalyzed Diamination of Alkenes
Xiaojian Liu, Chuanqi Hou, Yiyuan Peng,* Pinhong Chen,* Guosheng Liu* Org. Lett. 2020, 22, 9371-9375.

118

Copper-Catalyzed Benzylic C–H Bond Thiocyanation: Enabling Late-Stage Diversifications
Chao Jiang, Pinhong Chen, Guosheng Liu* CCS Chemistry, 2020, 2, 1884–1893.

117

Enantioselective Copper-Catalyzed Trifluoromethylation of Benzylic Radicals via Ring Opening of Cyclopropanols
Chao Jiang, Lei Wang, Honggang Zhang, Pinhong Chen, Yin-Long Guo, Guosheng Liu* Chem 2020, 6, 2407-2419.

116

Asymmetric Coupling of Carbon-Centered Radical Adjacent to Nitrogen: Copper-Catalyzed Cyanation and Etherification of Enamides
Guoyu Zhang, Song Zhou, Liang Fu, Pinhong Chen, Yibiao Li,* Jianping Zou,* Guosheng Liu* Angew. Chem. Int. Ed. 2020, 59, 20439-20444.

115

Palladium(II)-Catalyzed Enantioselective Azidation of Unactivated Alkenes
Xiaonan Li, Xiaoxu Qi, Chuanqi Hou, Pinhong Chen,* Guosheng Liu* Angew. Chem. Int. Ed. 2020, 59, 17239-17244.

114

Copper-Catalyzed Asymmetric Cyanation of Alkenes via Carbonyl-Assisted Coupling of Alkyl-Substituted Carbon-Centered Radicals
Song Zhou, Guoyu Zhang, Liang Fu, Pinhong Chen, Yibiao Li,* Guosheng Liu* Org. Lett. 2020, 22, 6299–6303.

113

Enantioselective Copper-Catalyzed Alkynylation of Benzylic C-H Bonds via Radical Relay
Liang Fu, Zhihan Zhang, Pinhong Chen, Zhenyang Lin*, Guosheng Liu* J. Am. Chem. Soc. 2020, 142, 28, 12493-12500.

112

Palladium(II)-Catalyzed Aminotrifluoromethoxylation of Alkenes: Mechanistic Insight into the Effect of N-Protecting Groups.
Chaohuang Chen, Chuanqi Hou, Pinhong Chen, Guosheng Liu* Chin. J. Chem. 2020, 38, 346-350.

111

Enantioselective Copper-Catalyzed Radical Ring-Opening Cyanation of Cyclopropanols and Cyclopropanone Acetals.
Lianqian Wu, Lei Wang, Pinhong Chen, Yin-Long Guo,* GuoshengLiu* Adv. Synth. Catal. 2020, 362, 2189-2194.

110

Enantioselective Palladium(II)-Catalyzed Oxidative Aminofluorination of Unactivated Alkenes with Et4NF·3HF as a Fluoride Source.
Chuanqi Hou, Pinhong Chen, Guosheng Liu* Angew. Chem. Int. Ed. 2020, 59, 2735-2739.

109

Recent Advances and Perspectives in Transition Metal-Catalyzed 1,4-Functionalizations of Unactivated 1,3-Enynes for the Synthesis of Allenes.
Liang Fu, Steffen Greßies, Pinhong Chen, Guosheng Liu* Chin. J. Chem. 2020, 38, 91-100.

2019

108

Site-specific Allylic C-H Bond Functionalization with a Copper-Bound N-Centred Radical
Jiayuan Li, Zhihan Zhang, Lianqian Wu, Wen Zhang, Pinhong Chen, Zhenyang Lin,* Guosheng Liu* Nature, 2019, 574, 516-521.

107

Iodine(III) reagent (ABX—N3)-induced intermolecular anti-Markovnikov hydroazidation of unactivated alkenes
Xiaonan Li, Pinhong Chen, Guosheng Liu* Sci. China Chem. 2019, 62, 1537-1541.

106

Enantioselective Cyanation of Remote C-H Bonds via Cooperative Photoredox Catalysis and Copper Catalysis (cover paper)
Zhongming Cheng; Pinhong Chen; Guosheng Liu* Acta Chim. Sinica 2019, 77, 856-860.

105

Proton-Coupled Electron Transfer Enables Tandem Radical Relay for Asymmetric Copper-Catalyzed Phosphinoylcyanation of Styrenes
Guoyu Zhang, Liang Fu, Pinhong Chen, Jianping Zou*, Guosheng Liu* Org. Lett. 2019, 21, 5015-5020.

104

Enantioselective Arylation of Benzylic C-H bonds via CopperCatalyzed Radical Relay
Wen Zhang, Lianqian Wu, Pinhong Chen, Guosheng Liu* Angew. Chem. Int. Ed. 2019, 58, 6425–6429.

103

Palladium(II)-Catalyzed Enantioselective Aminotrifluoromethoxylation of Unactivated Alkenes using CsOCF3 as a Trifluoromethoxide Source
Chaohuang Chen, Philipp Miro Pflüger, Pinhong Chen, Guosheng Liu* Angew. Chem. Int. Ed. 2019, 58, 2392 –2396.

102

Enantioselective Construction of Quaternary All-Carbon Centers via Copper-Catalyzed Arylation of Tertiary Carbon-Centered Radicals
Lianqian Wu, Fei Wang, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2019, 141, 1887−1892.

101

Palladium-Catalyzed Intramolecular Fluoroarylation of Alkenes
Wencheng Yang, Xiaoxu Qi, Pinhong Chen,* Guosheng Liu* Chin. J. Org. Chem. 2019, 39, 122-128.

2018

100

Pd-Catalyzed Intermolecular Arylcarbonylation of Unactivated Alkenes: Incorporation of Bulky Aryls at Room Temperature
Xiang Li, Pinhong Chen*, Guosheng Liu* Angew. Chem. Int. Ed. 2018, 57, 15871–15876.

99

Copper-Catalyzed Radical Relay for Asymmetric Radical Transformations
Fei Wang, Pinhong Chen, Guosheng Liu* Acc. Chem. Res. 2018, 51, 2036–2046.

98

Enantioselective Trifluoromethylalkynylation of Alkenes via Copper-Catalyzed Radical Relay
Liang Fu, Song Zhou, Xiaolong Wan, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc., 2018, 140, 10965–10969.

97

Copper-mediated intramolecular aminofluorination of 1,3-dienes by using nucleophilic fluorine reagents.
Zuxiao Zhang, Pinhong Chen,* Guosheng Liu* Chem. Commun. 2018, 54, 8709-8712.

96

Enantioselective Pd(II)-Catalyzed Intramolecular Oxidative 6-endo Aminoacetoxylation of Unactivated Alkenes.
Xiaoxu Qi, Chaohuang Chen, Chuanqi Hou, Liang Fu, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2018, 140, 7415−7419.

95

Decarboxylative Fluorination of Arylcarboxylic Acids Promoted by ortho-Hydroxy and Amino Groups.
Dinghai Wang, Zheliang Yuan, Qilun Liu, Pinhong Chen, Guosheng Liu* Chin. J. Chem. 2018, 36, 507-514.

94

Recent advances in hypervalent iodine(III)-catalyzed functionalization of alkenes.
Xiang Li, Pinhong Chen,* Guosheng Liu*Beilstein J. Org. Chem. 2018, 14, 1813–1825.

93

Divergent Synthesis of CF3-Substituted Allenyl Nitriles by Ligand-Controlled Radical 1,2- and 1,4-Addition to 1,3-Enynes.
Fei Wang, Dinghai Wang, Yu Zhou, Ling Liang, Ronghua Lu, Pinhong Chen, Zhenyang Lin,* Guosheng Liu* Angew. Chem. Int. Ed. 2018, 57, 7140 –7145.

92

Regioselective Palladium-Catalyzed C-H Bond Trifluoroethylation of Indoles: Exploration and Mechanistic Insight
Hao Zhang, Hao-Yang Wang,* Yixin Luo, Chaohuang Chen, Yimiao Cao, Pinhong Chen, Yin-Long Guo, Yu Lan,* Guosheng Liu* ACS Catal. 2018, 8, 2173−2180

91

Palladium-Catalyzed Intermolecular Ditrifluoromethoxylation of Unactivated Alkenes: CF3O‑Palladation Initiated by Pd(IV)
Chaohuang Chen, Yixin Luo, Liang Fu, Pinhong Chen, Yu Lan,* Guosheng Liu*  J. Am. Chem. Soc, 2018,140,1207-1210

2017

90

Enantioselective Decarboxylative Cyanation Employing Cooperative Photoredox Catalysis and Copper Catalysis
Dinghai Wang, Na Zhu, Pinhong Chen, Zhenyang Lin, Guosheng Liu*  J. Am. Chem. Soc, 2017,139,15632-15635

89

Palladium-Catalyzed Intermolecular Oxidative Diazidation of Alkenes
Haihui Peng, Zheliang Yuan, Pinhong Chen, Guosheng Liu*  Chin. J. Chem. 2017, 35, 876-880

88

Recent Advances and Perspectives of Transition Metal-Catalyzed Asymmetric Fluorination Reactions
Chaohuang Chen, Liang Fu, Pinhong Chen, Guosheng Liu*  Chin. J. Chem. 2017, 35, 1781-1788

87

Palladium-Catalyzed Intermolecular Azidocarbonylation of Alkenes via a Cooperative Strategy
Ming Li,Feng Yu, Pinhong Chen, Guosheng Liu*  J. Org. Chem., 2017,82,11682-11690

86

Palladium-Catalyzed Intermolecular Oxidative Fluorocarbonylation of Unactivated Alkenes: Efficient Access of β-Fluorocarboxylic esters
Xiaoxu Qi,Feng Yu, Pinhong Chen, Guosheng Liu*  Angew. Chem. Int. Ed. 2017,56,12692–12696

85

Catalytic Oxidative Trifluoromethoxylation of Allylic C-H Bonds using a Palladium Catalyst
Xiaoxu Qi, Pinhong Chen, Guosheng Liu*  Angew. Chem. Int. Ed. 2017, 56, 9517-9521

84

Copper-Catalyzed Arylation of Benzylic C–H bonds with Alkylarenes as the Limiting Reagents
Wen Zhang, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2017, 139, 23, 7709-7712

83

Asymmetric Copper-Catalyzed Intermolecular Aminoarylation of Styrenes: Efficient Access to Optical 2,2-Diarylethylamines
Dinghai Wang, Lianqian Wu, Fei Wang, Xiaolong Wan, Pinhong Chen, Zhenyang Lin, Guosheng Liu* J. Am. Chem. Soc. 2017, 139, 20, 6811-6814

82

Enantioselective Palladium(II)-Catalyzed Intramolecular Aminoarylation of Alkenes by Dual N-H and Aryl C-H Bond Cleavage
Wen Zhang, Pinhong Chen, Guosheng Liu* Angew. Chem. Int. Ed. 2017, 56, 5336-5340.

81

Setting Cyclohexane Stereochemistry with Oxidation
Fei Wang, Guosheng Liu* ACS Cent. Sci. 2017, 3, 161-162.(First Reactions: Wang and Liu discuss advances in enantioselective oxidation of nonactivated C−H bonds)

80

Asymmetric Cu-Catalyzed Intermolecular Trifluoromethylarylation of Styrenes: Enantioselective Arylation of Benzylic Radicals
Lianqian Wu, Fei Wang, Xiaolong Wan, Dinghai Wang, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2017, 139, 2904-2907.

79

Enantioselective Copper-Catalyzed Intermolecular Amino- and Azidocyanation of Alkenes in a Radical Process
Dinghai Wang, Fei Wang, Pinghong Chen, Zhenyang Lin,* Guosheng Liu* Angew. Chem. Int. Ed. 2017, 56, 2054-2058.

2016

78

Enantioselective Copper-Catalyzed Intermolecular Cyanotrifluoromethylation of Alkenes via Radical Process
Fei Wang, Dinghai Wang, Xiaolong Wan, Lianqian Wu, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2016, 138, 15547-15550.

77

Author Profile of Guosheng Liu
Guosheng Liu* Angew. Chem. Int. Ed. 2016, 55, 15206.

76

Palladium(II)-Catalyzed Oxidative Difunctionalization of Alkenes:Bond Forming at a High-Valent Palladium Center
Guoyin Yin, Xin Mu, Guosheng Liu*  Acc. Chem. Res. 2016, 49, 2413−2423.

75

Cooperative Strategy for the Highly Selective Intermolecular Oxycarbonylation Reaction of Alkenes using palladium catalyst.
Ming Li, Feng Yu, Xiaoxu Qi, Pinhong Chen, Guosheng Liu* Angew. Chem. Int. Ed. 2016, 55, 13843-13848.

74

Enantioselective cyanation of benzylic C–H bonds via copper-catalyzed radical relay
Wen Zhang,# Fei Wang,# Scott D. McCann, Dinghai Wang, Pinhong Chen, Shannon S. Stahl,* Guosheng Liu*  Science 2016, 353, 1014-1018..(# These author contributed equally to this work)  #Free access to this paper#

73

Efficient Pathway for the Preparation of Aryl(isoquinoline)iodonium(III) Salts and Synthesis of Radiofluorinated Isoquinolines
Zheliang Yuan, Ran Cheng, Pinhong Chen, Guosheng Liu,* Steven Liang*  Angew. Chem. Int. Ed. 2016, 55, 11882 –11886.

72

Mechanistic Investigation on the Silver-Catalyzed Oxidative Intramolecular Aminofluorination of Alkynes
Tao Xu, Yichen Wu, Zheliang Yuan, Hairong Guan, Guosheng Liu* Organometallics 2016, 35, 1347-1349.(Invited Paper)

71

Pd(II)-Catalyzed Aminofluorination of Alkenes in Total Synthesis 6-(R)-Fluoroswainsonine and 5-(R)-Fluorofebrifugine
Liang Wu, Pinhong Chen,* Guosheng Liu* Org. Lett. 2016, 18, 960-963.

2015

70

Palladium-Catalyzed Intramolecular Aminotrifluoromethoxylation of Alkenes
Chaohuang Chen, Pinhong Chen, Guosheng Liu*  J. Am. Chem. Soc. 2015, 137, 15648-15651.

69

Copper-Catalyzed Trifluoromethylazidation of Alkynes: Efficient Access to CF3-Substituted Azirines and Aziridines
Fei Wang, Na Zhu, Pinhong Chen, Jinxing Ye, Guosheng Liu*  Angew. Chem. Int. Ed. 2015, 54, 9356-9360.

68

Abnormal Messianic Carbene Silver Complex: Synthesis, Reactivity, and Mechanistic Insight on Oxidative Fluorination
Qilun Liu, Zheliang Yuan, Hao-yang Wang,* Yang Li, Yicheng Wu, Tao Xu, Xuebing Leng, Pinhong Chen, Yin-long Guo, Zhenyang Lin,* Guosheng Liu*  ACS Catal. 2015, 5, 6732–6737.

67

Palladium-Catalyzed Intermolecular Aminocarbonylation of Alkenes: Efficient Access of β-Amino Acid Derivatives
Jiashun Cheng, Xiaoxu Qi, Ming Li, Pinhong Chen, Guosheng Liu*  J. Am. Chem. Soc. 2015, 137, 2480–2483.

66

Highly Selective Pd-Catalyzed Intermolecular Fluorosulfonylation of Styrenes
Zheliang Yuan, Hao-Yang Wang, Xin Mu, Pinhong Chen, Yin-Long Guo, Guosheng Liu*   J. Am. Chem. Soc. 2015, 137, 2468–2471.

65

Advances and challenges in palladium-catalyzed intermolecular selective allylic C-H functionalization of alkenes
Xiaoxu Qi, Pinhong Chen, Guosheng Liu*  Sci. China Chem. 2015, 58, 1249-1251.

64

Copper-Catalyzed Intermolecular Trifluoromethylazidation and Trifluoromethylthiocyanation of Allenes: Efficient Access to CF3-Containing Allyl Azides and Thiocyanates
Na Zhu, Fei Wang, Pinhong Chen, Jinxing Ye,* Guosheng Liu*  Org. Lett. 2015, 17, 3580-3583.

63

Palladium-Catalyzed Trifluoromethylthiolation of Arenes via C-H Activation
Jiabin Xu, Pinhong Chen, Jingxing Ye,* Guosheng Liu*  Acta Chim. Sinica 2015, 73, 1294-1297.

62

Pd(II)-catalyzed intermolecular enantioselective hydroamination of styrenes
Feng Yu, Pinhong Chen,* Guosheng Liu*  Org. Chem. Front. 2015, 2, 819-822.

61

Copper-Catalyzed Intermolecular Trifluoromethylthiocyanation of Alkenes: Convenient Access to CF3-Containing Alkyl Thiocyanates
Zhaoli Liang, Fei Wang, Pinhong Chen, Guosheng Liu* Org. Lett. 2015, 17, 2438-2441.

60

Palladium-Catalyzed Intramolecular Aminoacetoxylation of Unactivated Alkenes with Hydrogen Peroxide as Oxidant
Haitao Zhu, Pinhong Chen, Guosheng Liu** Org. Lett. 2015, 17, 1485-1488.

59

Advancements in Aminofluorination of Alkenes and Alkynes: Convenient Access to beta-Fluoroamines
Pinhong Chen,* Guosheng Liu*  Eur. J. Org. Chem. 2015, 4295-4309.

58

Pd-catalyzed intramolecular aminofluorination of allylic sulfamides
Jiashun Cheng, Pinhong Chen, Guosheng Liu*  Chin. J. Catal. 2015, 36, 40-47.

2014

57

Copper-Catalyzed Trifluoromethylthiolation of Aryl Halides with Diverse Directing Groups
Jiabing Xu, Xin Mu, Pinhong Chen, Jinxing Ye*, Guosheng Liu* Org. Lett. 2014, 16, 3942-3945.

56

Branch-selective Allylic C-H Caboxylation of Terminal Alkenes by Pd/Sox Catalyst.
Hiroki Kondo, Feng Yu, Junichiro Yamaguchi, Guosheng Liu,* Kenichiro Itami,*  Org. Lett. 2014, 16, 4212–4215.

55

Palladium-Catalyzed Cascade C-H Trifluoroethylation of Aryl Iodides and Heck Reaction: Efficient Synthesis of ortho-Trifluoroethylstyrenes
Hao Zhang, Pinhong Chen, Guosheng Liu*  Angew. Chem. Int. Ed. 2014, 53, 10174-10178.

54

Copper-Catalyzed Intermolecular Trifluoromethylarylation of Alkenes: Mutual Activation of Arylboronic Acid and CF3+ Reagent
Fei Wang, Dinghai Wang, Xin Mu, Pinhong Chen, Guosheng Liu* J. Am. Chem. Soc. 2014, 136, 10202-10205.(Featured in Synfact, 2014, 10, 1083)

53

Copper-catalyzed Intermolecular Cyanotrifluoromethylation of Alkenes: Convenient Synthesis of CF3-containing Alkyl Nitriles
Zhaoli Liang, Fei Wang, Pinhong Chen, Guosheng Liu* J. Fluorine Chem. 2014, 167, 55-60.

52

Copper-mediated/-catalyzed fluorination reactions: new routes to aryl fluorides
Mu, Xin; Liu, Guosheng* Org. Chem. Front. 2014, 1, 430-433. (highlight)

51

Copper-Catalyzed Intermolecular Trifluoromethylazidation of Alkenes: Convenient Access to CF3-Containing Alkyl Azides
Wang, Fei; Qi, Xiaoxu; Liang, Zhaoli; Chen, Pinhong; Liu, Guosheng*   Angew. Chem. Int. Ed. 2014, 53, 1881-1886.

50

Pd-Catalyzed Intramolecular Aminohydroxylation of Alkenes with Hydrogen Peroxide as Oxidant and Water as Nucleophile
Zhu, Haitao; Chen, Pinhong; Liu, Guosheng*  J. Am. Chem. Soc. 2014, 136, 1766-1769.

49

Pallasium-catalyzed cascade cyclization for the construction of spiro-N,O-acetals
Cheng, Jiashun; Chen, Pinhong; Liu, Guosheng* Org. Chem. Front. 2014, 1, 289-293.

48

Copper-catalyzed fluorination of 2-pyridyl aryl bromides
Mu, Xin; Zhang, Hao; Chen, Pinhong; Liu, Guosheng* Chem. Sci. 2014, 5, 275-280.

47

AgF-Mediated Dialkylation of Activate Alkenes: An Efficient Access to Nitrile-Containing Spirooxindoles
Liang Wu, Pinhong Chen, Guosheng Liu* Chin. J. Chem. 2014, 32, 681-684

2013

46

Copper-Catalyzed Regioselective Fluorination of Allylic Halides
Zhang, Zuxiao;# Wang, Fei;# Mu, Xin; Chen, Pinhong; Liu, Guosheng*  Angew. Chem. Int. Ed. 2013, 52, 7549-7553.(# These author contributed equally to this work)

45

One-Pot Synthesis of 1-(Trifluoromethyl)4-fluoro-1,2-dihydroisoquinolines and 4,4-Difluoro-1,2,3,4-tetrahydro- isoquinolines
Liu, Qilun; Wu, Yichen; Chen, Pinhong; Liu, Guosheng* Org. Lett. 2013, 15, 6210-6213.

44

Recent Advances in Transition-Metal-Catalyzed Trifluoromethylation and Related Transformations
Chen, Pinhong; Liu, Guosheng* Synthesis 2013, 45, 2919-2939. (Invited Review)

43

Palladium-Catalyzed Intermolecular Aminoacetoxylation of Alkenes and the Influence of Phl(OAc)2 on Aminopalladation Stereoselectivity
Martinez, Claudio; Wu, Yichen; Weinstein, Adam B.; Stahl, Shannon S.;* Liu, Guosheng;* Muñiz, Kilian* J. Org. Chem. 2013, 78, 6309–6315.

42

Regioselective palladium-catalyzed intramolecular oxidative aminofluorination of unactivated alkenes
Wu, Tao; Cheng, Jiashun; Chen, Pinhong; Liu, Guosheng* Chem. Commun. 2013, 49, 8707-8709.

41

Palladium-catalyzed intermolecular fluoroesterification of styrenes: exploration and mechanistic insight
Peng, Haihui; Yuan, Zheliang; Wang,Hao-yang; Guo, Yin-long; Liu, Guosheng *   Chem. Sci. 2013, 4, 3172-3718.

40

Palladium-Catalyzed Intramolecular Fluorooxylation of Styrenes
Yuan, Zheliang; Peng, Haihui; Liu, Guosheng*  Chin. J. Chem. 2013, 31, 908-914.(Invited paper)

39

Palladium-Catalyzed C-C Triple Bond Cleavage: Efficient Synthesis of 4H-Benzo[d][1,3]oxazin-4-ones
Liu, Qilun; Chen, Pinhong; Liu, Guosheng*   ACS Catal. 2013, 3, 178-181. (Invited Paper)

2012

38

Transition metal-catalyzed fluorination of multi carbon-carbon bonds: new strategies for fluorinated heterocycles
Liu, Guosheng* Org. Biomol. Chem. 2012, 10, 6243-6248. (Invited Review)

37

Ag(I)-Catalyzed Aminofluorination of Alkynes: Efficient Synthesis of 4-Fluoroisoquinolines and 4-Fluoropyrrolo[α]isoquinolines
Xu, Tao; Liu, Guosheng*   Org. Lett. 2012, 14, 5416-5419.

36

Palladium-Catalyzed Oxidative Arylalkylation of Unactivated Alkenes: Dual C-H Bond Cleavage of Anilines and Acetonitrile
Zhang, Hao; Chen, Pinhong; Liu, Guosheng*   Synlett 2012, 23, 1749-2752. (Invited paper for C-H bond activation Cluster)

35

Palladium-Catalyzed Oxidative Aminofluorination of Styrenes
Zhu Haitao; Liu Guosheng* Acta Chimica Sinica 2012, 70, 2404-2407.

34

Organocatalyzed arylalkylation of activated alkenes via decarboxylation of PhI(O2CR)2: efficient synthesis of oxindoles
Wu, Tao; Zhang, Hao; Liu, Guosheng*   Tetrahedron 2012, 68, 5229–5233. (Invited paper to the celebration of Prof. Zhangjie Shi for his Tetrahedron Award)

33

Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature
Mu, Xin; Wu, Tao; Wang, Hao-yang; Guo, Yin-long; Liu, Guosheng*   J. Am. Chem. Soc. 2012, 134, 878-881.

32

Silver-Catalyzed Fluorination Reactions
Xu, Tao; Liu, Guosheng*  Synlett, 2012, 955-958. (Synpacts)

31

Highly Selective Palladium-Catalyzed Intramolecular Chloroamination of Unactivated Alkenes by Using Hydrogen Peroxide as an Oxidant
Yin, Guoyin; Wu, Tao; Liu, Guosheng*   Chem. Eur. J. 2012, 18, 451-455.

2011

30

Palladium-Catalyzed Oxidative Arylalkylation of Activated Alkenes: Dual C-H Bond Cleavage of an Arene and Acetonitrile
Wu, Tao; Mu, Xin; Liu, Guosheng*  Angew. Chem. Int. Ed. 2011, 50, 12578-12581.

29

Silver-Catalyzed Intramolecular Aminofluorination of Activated Allenes
Xu, Tao; Mu, Xin; Peng, Haihui; Liu, Guosheng*  Angew. Chem. Int. Ed. 2011, 50, 8176-8179.

28

Highly Selective Palladium-Catalyzed Intramolecular Aminonitroxylation of Alkenes
Chen, Shujun; Wu, Tao; Liu, Guosheng;* Zhen, Xingliang   SynLett , 2011, 891-894. (Invited Paper for the contribution of Prof. Xiyan Lu and Prof. Lixin Dai in Organic Chemistry)

27

Palladium-Catalyzed Oxidative Trifluoromethylation of Indoles at Room Temperature
Mu, Xin; Chen, Shujun; Zhen, Xingliang; Liu, Guosheng*  Chem. Eur. J. 2011, 17, 6039-6042.

26

Palladium-Catalyzed Intramolecular Aminofluorination of Styrenes
Xu, Tao; Qiu, Shuifa; Liu, Guosheng*  Chin. J. Chem. 2011, 29, 2785-2790. (Invited Paper on the occasion of Prof . Weiyuan Huang’s 90th birthday)

25

Palladium-Catalyzed Tandem Fluorination and Cyclization of Enynes
Peng, Haihui; Liu, Guosheng*   Org. Lett. 2011, 13, 772-775. (Featured in Synfact, 2011, 12, 518)

24

Organocatalyzed cycloaddition of carbon dioxide to aziridines
Wu, Yichen; Liu, Guosheng*  Tetrahedron Lett. 2011, 52, 6450-6452.

23

Mechanistic Studies of Wacker-Type Intramolecular Aerobic Oxidative Amination of Alkenes Catalyzed by Pd(OAc)2/Pyridine
Ye, Xuan; Liu, Guosheng; Popp, Brian V.; Stahl Shannon S.** J. Org. Chem. 2011, 76, 1031–1044.

22

Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications
McDonald, Richard I.; Liu, Guosheng; Stahl, Shannon S.*   Chem. Rev., 2011, 111, 2981–3019.

21

Palladium-catalyzed inter- and intramolecular hydroamination of styrenes coupled with alcohol oxidation using N-fluorobenzenesulfonimide as the oxidant
Xu, Tao; Qiu, Shuifa; Liu, Guosheng*  J. Organomet. Chem. 2011, 696, 46-49.(Invited Paper for the special issue on the H-B addition to C-C double bond)

2010

20

Palladium-Catalyzed Allylic C–H Bond Functionalization of Olefins
Liu, Guosheng;* Wu Yichen  C-H Activation: Topics in Current Chemistry, 2010, 292, 195-209.

19

Palladium-Catalyzed Intermolecular Aminofluorination of Styrenes
Qiu, Shuifa; Xu, Tao; Zhou, Juan; Guo, Yinlong; Liu, Guosheng*  J. Am. Chem. Soc. 2010, 132, 2856–2857.

18

Scope and Mechanism of Allylic C−H Amination of Terminal Alkenes by the Palladium/PhI(OPiv)2 Catalyst System: Insights into the Effect of Naphthoquinone
Yin, Guoyin; Wu, Yichen; Liu, Guosheng*  J. Am. Chem. Soc. 2010, 132, 11978-11987. (This paper was listed as one of the journal’s Top 20 most downloaded papers in August of 2010)

2009

17

Palladium-Catalyzed Intramolecular Aminofluorination of Unactivated Alkenes
Wu, Tao; Yin, Guoyin; Liu, Guosheng*  J. Am. Chem. Soc. 2009, 131, 16354-16355. (Featured in Synfact, 2010, 3, 276)

16

Bronsted Base-Modulated Regioselective Pd-Catalyzed Intramolecular Aerobic Oxidative Amination of Alkenes: Formation of Seven-Membered Amides and Evidence for Allylic C-H Activation
Wu, Liang; Qiu, Shuifa; Liu, Guosheng*  Org. Lett. 2009, 11, 2707-2710.

15 

Palladium-Catalyzed Intramolecular Hydro- amination of Allenes Coupled to Aerobic Alcohol Oxidation
Qiu, Shuifa; Wei, Yunyang; Liu, Guosheng*  Chem. Eur. J. 2009, 15, 2751-2754.

2008

14 

Palladium-catalyzed intermolecular aerobic oxidative amination of terminal alkenes: efficient synthesis of linear allylamine derivatives
Liu, Guosheng;* Yin, Guoyin; Wu, Liang  Angew. Chem. Int. Ed. 2008, 47, 4733-4736.

13

Palladium-catalyzed oxidative cyclization of enyne with hydrogen peroxide as the oxidant
Yin, Guoyin; Liu, Guosheng*   Angew. Chem. Int. Ed. 2008, 47, 5442-5445. (Hot paper, and Featured in Synfact, 2008, 10, 1066)

Before independent work:

12

Cobalt-Catalyzed Carbonylative Polymerization of Azetidines
Chai, Jianfang; Liu, Guosheng; Chaicharoen, Kittisak; Wesdemiotis, Chrys; Jia, Li* Macromolecules 2008, 41, 8980-8985.

11

Two-Faced Reactivity of Alkenes: cis- versus trans-aminopalladation in Aerobic Pd-Catalyzed Intramolecular Aza-Wacker Reactions
Liu, Guosheng; Stahl, Shannon. S.*  J. Am. Chem. Soc. 2007, 129, 6328-6335.

10

Highly Regeioselective Pd-Catalyzed Intermolecular Aminoacetoxylation of Alkene and Evidence for the cis-Aminopalladation and SN2 C-O Bond Formation
Liu, Guosheng; Stahl, Shannon. S.*  J. Am. Chem. Soc. 2006, 128, 7179-7181.

09

Cobalt-Catalyzed Carbonylative Copolymerizaiton of N-Alkylazetidines and Tetrahydrofuran
Liu, Guosheng; Jia, Li*  Angew. Chem. Int. Ed. 2005, 45, 129-131.

08

Design of Catalytic Carbonylative Polymerizations of Heterocylces. Synthesis of Polyesters and Amphiphilic Poly(amide-block-ester)s
Liu, Guosheng; Jia, Li*   J. Am. Chem. Soc. 2004, 126, 14716-14717.

07

A novel highly regio- and diastereoselective haloamination of alkenes catalyzed by divalent palladium
Lei, Aiwen; Liu, Guosheng; Lu, Xiyan*  Tetrahedron Lett. 2004, 45, 1785-1788.

06

One-pot synthesis of tetrahydrofuran derivatives via a divalent palladium-catalyzed three-component coupling
Liu, Guosheng; Lu, Xiyan*  Tetrahedron Lett. 2003, 44, 467-470.

05

Palladium(II)-Catalyzed Coupling of Allenoic Acids and a,b-Unsaturated Carbonyl Compounds through Tandem Intramolecular oxypalladation and Conjugate Addition Reactions
Liu, Guosheng; Lu, Xiyan*  Tetrahedron Lett. 2003, 44, 127-130.

04

Palladium(II)-Catalyzed Highly Regio- and Diastereoselective Cyclization of Difunctional Allylic N-Tosylcarbamates. A Convenient Synthesis of Optically Active 4-Vinyl-2-oxazolidinones and Total Synthesis of 1,4-Dideoxy-1,4-imino- L-xylitol
Lei, Aiwen; Liu, Guosheng; Lu, Xiyan*  J. Org. Chem. 2002, 67, 974-980.

03

Palladium(II)-Catalyzed Coupling Reactions of Intramolecular Carbopalladation of Alkyne with Allylic Compounds
Liu, Guosheng; Lu, Xiyan*  Tetrahedron Lett.  2002, 43, 6791-6794.

02

Palladium(II)-Catalyzed Tandem Reaction of Intramolecular Aminopalladation of Allenyl N-Tosylcarbamates and Conjugate Addition
Liu, Guosheng; Lu, Xiyan*  Org. Lett. 2001, 3, 3879-3882.

01

Asymmetric cyclopropanation of styrene catalyzed by Cu-(chiral Schiff-base) complexes
Li, Zhengning;* Liu, Guosheng; Zheng, Zhuo; Chen, Huilin  Tetrahedron 2000, 56, 7187-7191.

Book Charpter

06

刘国生 (Liu Guosheng), “金属催化的合成反应”, 高速发展的中国化学1982-2012, 科学出版社, 2012年.

05

刘国生 (Liu Guosheng), “绿色氧化”, 10000 个科学难题-化学卷, 267-269页, “10000 个科学难题”化学编委会主编, 科学出版社, 2009 年.

04

Guosheng Liu,* Pinhong Chen “C-C and C-X Bond Formation by Allylic C-H Activation” in Reference Library: Catalytic Transformations via C—H Activation 2, Workbench Edition (Jin-Quan Yu, Ed.), Thieme: New York, 2016.

03

Pinhong Chen, Guosheng Liu,* Keary M. Engle, Jin-Quan Yu* “High-Valent Palladium in Catalysis”, in Houben-Weyl: Science of Synthesis knowledge Updates, volume 1: Compounds with Transition-Metal-Carbon p-Bond and Compounds of Group 10-8 (Ni, Pt, Co, Rh, Ir, Fe, Os), (B. M. Trost, P. J. Plietker, Eds.), Thieme: New York, 2013.

02

Xin Mu, Guosheng Liu* “Chapter 11, Dioxygen-Coupled Palladium and Copper-Catalyzed Csp2-H Functionalization: Reactions and Mechanisms” in C-H and C-X Bond Functionalization: Transition Metal Mediation (X. Ribas, Ed.) RSC Publishing, 2013.

01

Guosheng Liu,* Yichen Wu “Bathocupronie”, in e-EROS Encyclopedia of Reagents for Organic Synthesis (D. Crich, P. L. Fuchs, A. B. Charette, T Rovis, Eds.), Wiley-Interscience, 2011.